Hidratii Carbon

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    WDJXG[]JQCQGC QGNDJM C BI@AIXGJ

    Hcmw`qcqgc Qgndi`ifjg j Bcdcfgbgdq

    d Jdaw}q{jc C`jbgdqc{

    Mcqga{c Mnjbjg

    Nja{cjj ag mc{kid mibpidgdj p{jdmjpc`j cj

    `gbdw`wj

    Diqg ag mw{}

    MnjjdwW$Q$B$

    ;??6

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    _{gugdqg`g diqg ag mw{} `c aj}mjp`jdc Mnjbjc `gbdw`wj }dq

    ag}qjdcqg }qwagdj`i{ }pgmjc`jqjj 71=$3, Qgndi`ifjc p{g`wm{{jj

    `gbdw`wj j c`qi{ }pgmjc`jqj ajd jdaw}q{jc bcqg{jc`g`i{ ag mid}q{wmjg,

    `c }gmjc ag uj j mw h{gmxgd {gaw}$ ]dq g`cki{cqg d midhi{bjqcqg

    mw p{if{cbw` ag dxbdq `c Mnjbjc `gbdw`wj$ d `wm{c{g }wdq

    g`wmjacqg c}pgmqg`g }q{wmqw{jj, p{ip{jgqj`g hjujmi"mnjbjmg c`g

    mg`w`iugj j ngbjmg`w`iug`i{ mc{g }g mid}jag{ mibpidgdqg mnjbjmg

    p{jdmjpc`g c`g `gbdw`wj

    G`cki{c{g5 midh$wdjx$ , a{$ Bjncj` Fngjw

    [gacmqi{ {g}pid}ckj`5 midh$ wdjx$, a{$ Cdc Xg{gecd

    [gmgdugdq5 midh$ wdjx$ a{$ @c{j}c Ucai{iedj

    [gacmqi{5 G`xj{c Fngi{fnjqgcdw

    """""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""""Kwd ag qjpc{ 3>$?8$?6 Hi{bcqw` 8? ^ >1 3)38$N{qjg ih}gq$ Qjpc{ [j}i$ Qj{cew` 3?? g~$Mi`j ag qjpc{ >,;7 Mibcdac d{$3?=

    ;??1, Mnjjdw, ka$ qghcd mg` Bc{g,38>]gmjc [gacmqc{g j Gajqc{g c W$Q$B$

    BA";?8>, Mnjjdw, }q{$ ]qwagdj`i{, :):

    ;

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    W$Q$B$, ;??6

    Mibpidgdjj mnjbjmj p{jdmjpc`j cj `gbdw`wj }dq5

    mg`w`iuc, ngbjmg`w`iug`g j `jfdjdc$ Ajdq{g cmgqjc mg`w`iuc jngbjmg`w`iug`g p{gujdq ajd pwdmq ag xgag{g mnjbjm djqg

    pi`jucnc{jag mc{g `c {daw` `i{ hcm pc{qg ajd f{wpc nja{cj`i{ ag

    mc{kid$ j `jfdjdc, mw qicqg m p{gujdq wd pi`jbg{ ag dcqw{

    c{ibcqjm, g}qg }jdqgqjucq d p`cdqg qiq ajd nja{cj ag mc{kid$

    3$ Nja{cjj ag mc{kidNja{cjj ag mc{kid }dq p{iawj dcqw{c`j ag jbpi{qcd xjqc`

    pgdq{w p`cdqg j cdjbc`g$ _`cdqg`g, d cmg`cj qjbp j c{ki{jj,}jdqgqjugcu nja{cj ag mc{kid ajd MI; j N;I$ [gcmjc g}qg mcqc`jucqag m`i{ihj` j dgmg}jq gdg{fjg }i`c{5

    8MI; , 8N;I M8.N;I*8 , 8I;wbjd

    mi{ihj

    Agdwbj{gc ag nja{cj ag mc{kid p{ixjdg dm ag pg x{gbgcmda }q{wmqw{c `i{ dw g{c mwdi}mwq, acqi{jq hcpqw`wj m `c p{jbjjmibpwj jui`cj d }qc{g pw{ }"c f}jq cmg`cj {cpi{q dq{g i~jfgd jnja{ifgd mc j d bi`gmw`c ag cp$ Cmgc}q agdwbj{g }"c aixgajq mg}qg jbp{ip{jg pgdq{w m w`qg{ji{ }"cw ag}mipg{jq nja{cj ag mc{kid dmc{g {cpi{qw` ajdq{g nja{ifgd j i~jfgd g}qg ajhg{jq ag mg` ajd cp, agg~gbp`w ag}i~j{jkiuc c{g mibpiujjc5 M7N3?I1$ Mibj}jc

    jdqg{dcjidc` pgdq{w dibgdm`cqw{ d mnjbjg c p{ipw} agdwbj{gc agf`wmjag, ag `c f`wmiu, mc{g g}qg wdw` ajdq{g {gp{gugdqcdjj mgj bcjjbpi{qcdj cj cmg}qgj m`c}g ag mibpwj$ Cmgc}q agdwbj{g g}qgwqj`jucq bcj bw`q d kjimnjbjg, acqi{jq hcpqw`wj m f`wmiuc eicm wd{i` jbpi{qcdq d p{img}g`g kjimnjbjmg$ d mnjbjg }g bgdjdg dmidqjdwc{g qg{bgdw` ag nja{cj ag mc{kid, hjjda hi`i}jq j agdwbj{gcag ucnc{w{j, bcj c`g} d jdaw}q{jc p{g`wm{qic{g, mc{g p{ixjdg ag `cucnc{iu, ag c}gbgdgc wd {gp{gugdqcdq jbpi{qcdq c` cmg}qgj m`c}g$

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    3$3$ M`c}jhjmc{gcNja{cjj ag mc{kid }g bpc{q d bidiucnc{jag,

    i`jfiucnc{jag j pi`jucnc{jag$ I`jfi" j pi jucnc{jag`g

    nja{i`jugcu }wk cmjwdgc cmjuj`i{ bjdg{c`j }cw c wdi{ gdujbg,q{cd}hi{bdaw"}g d bidiucnc{jag$ Bidiucnc{jag`g dwnja{i`jucu `c mibpidgdqg bcj }jbp`g$ G`g mid}qjqwjg wdjqj`g agkcu c`g i`jfi" j pi`jucnc{jag`i{$ I`jfiucnc{jag`g acw `c nja{i`juaiw pd `c c}g bi`gmw`g ag bidiucnc{jag .i`jfi}" pwjd*, pg mda pi`jucnc{jag`g }dq mibpw}g ajdq{"wd dwb{ bc{g ag {g}qw{j agbidiucnc{jag$ Cqq d i`jfi" mq j d pi`jucnc{jag, bidiucnc{jag`g}g `gcf dq{g g`g p{jd g`jbjdc{gc wdgj bi`gmw`g ag cp ag `c aiw

    f{wp{j nja{i~j`jmg$ C}qhg` {g}qw{j`g ag bidiucnc{jag }g wdg}m p{jdjdqg{bgajw` wdwj cqib ag i~jfgd$Bidiucnc{jag`g cw d mibpiujjc bi`gmw`gj }c`g f{wpc

    mc{kidj` 4M2 I$ Gc picqg hj c`agnjajm MN2 I }cw mgqidjm[MI[$ Awp mwb f{wpc{gc mc{kidj jm g}qg c`agnjajm }cwmgqidjm, bidiucnc{jag`g }g m`c}jhjm d c`aiug j mgqiug$ d hwdmjgag dwb{w` cqibj`i{ ag mc{kid ajd bi`gmw` g`g piq hj q{jiug,qgq{iug, pgdqiug, ng~iug gqm$ d cmg}q bia }g aj}qjdf5

    mw M= c`aiq{jiug j mgqiq{jiug< mw M1 c`aiqgq{iug j mgqiqgq{iug< mw M7 c`aipgdqiug j mgqipgdqiug< mw M8 c`aing~iug j mgqing~iug, gqm$

    Mda }g c`mqwg}m agdwbj{j`g ag{jxcj`i{, dwbg{iqc{gc cqibj`i{ag mc{kid }g hcmg d cc hg` mc f{wpc{gc mc{kidj`jm } cjk mjh{c mgcbcj bjm$ Mg`g bcj {}pdajqg bidiucnc{jag }dq pgdqiug`g j

    ng~iug`g, mc{g }g f}g}m d dcqw{ `jkg{g }cw mibkjdcqg j cwagdwbj{j dg}j}qgbcqjmg$

    3$;$ ]q{wmqw{c bidiucnc{jag`i{_g kcuc cdc`jugj g`gbgdqc{g mcdqjqcqjxg j c bc}gj

    bi`gmw`c{g }"c }qckj`jq mpgdqiug`g cw hi{bw`c bi`gmw`c{ M7N3?I7,jc{ ng~iug`g M8N3;I8$ G`g midjd i mcqgd di{bc`, mggc mg }"c

    aixgajq p{jd {gawmg{gc `i{ mw NJ$ @c qgbpg{cqw{j {jajmcqg ajd ng~iug

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    p{jd {gawmg{g }g ikjdg .MN="MN;"MN;"MN;"MNJ"MN=* ;"jiaing~cd" }wk}qcd mw mcqgd di{bc`, dg{cbjhjmcq$

    G~j}qgdc f{wpg`i{ nja{i~j`jmg j dwb{w` `i{ }"c agqg{bjdcqp{jd {gcmjj ag g}qg{jhjmc{g j gqg{jhjmc{g$ @c q{cqc{gc ng~iug`i{ mwcdnja{ja cmgqjm }cw m`i{w{ ag cmgqj` c {guw`qcq wd ag{jxcqpgdqccmgqj`cq, mggc mg c pw} d gxjagd p{gugdc c mjdmj f{wpg IN5M8N3;I8 , 7 .MN=MI*;I M8N6I.IMIMN=*7 , 7MN=MIING~j}qgdc mg`i{ mjdmj f{wpg IN d ng~iug }"c midhj{bcq j p{jdbgqj`c{gc cmg}qi{c, d bgajw c`mc`jd, mda }"c ikjdwq wd ag{jxcqpgdqcbgqj`cq$ Hjgmc{g nja{i~j` ajd bi`gmw`c nja{cqw`wj ag mc{kid g}qg`gfcq mw mqg wd cqib ag mc{kid, dw piq g~j}qc aiw f{wpg IN `c

    cmg`cj mc{kid .{gfw`c G{`gdbgzg{*$Hcpqw` m pgdqiug`g j ng~iug`g cajjidgcu cmjamjcdnja{jm, acw i~jbg, hgdj`nja{cuidg j }dq i~jacqg ag }i`wjcHgn`jdfj i~jaw` ag c{fjdq cbidjcmc` .{gcmqjxw` Qi``gd}* c midaw}`c midm`wujc m cmg}qgc midjd i f{wpc{g mc{kidj`jm$

    Gbj` Hj}mng{ c p{ipw} pgdq{w bidiucnc{jag i }q{wmqw{cmjm`jm, pgdq{w m cmg}qgc acw cp{icpg qicqg {gcmjj`g }pgmjhjmgf{wp{jj mc{kidj`jmg5

    caing~iu

    MN; MN MN MN MN

    ININ INININ

    MIN

    mgqing~iu

    MN; MN MN MN M MN;INININININ I

    Awp mwb pwqgb ik}g{xc, dq{"i bi`gmw` ag bidiucnc{ja}dq p{gugdqg f{wpc mc{kidj` j f{wpg nja{i~j`$ Cmg}qgc, hjjda `caj}qcd cp{ipjcq wdc ag c`qc, piq {gcmjidc, hi{bda }gbjcmgqc`,

    midhi{b }mngbgj5

    [ INMIN

    [ , [ MNIN

    I[

    f{wp }gbjcmgqcjm

    }gbjcmgqc

    d mcuw` bidiucnc{jag`i{, iacq mw hi{bc{gc }gbjcmgqc`w`wj, jcdcqg{g i diw `gfqw{ mnjbjm M"I, mc{g dmnjag wd mjm`w ajd 8 }cw

    7 cqibj .mjm`w{j }qckj`g*5

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    nja{i~j

    }gbjcmgqcjm}cw fjmiujajm

    caing~iuc.hi{bc nja{i~jmc{kidj jm*

    I

    M M

    MM

    M

    N

    MN;IN

    N

    N N

    N

    IN IN

    INNI

    caing~iuc.hi{bc mjm jm }gbjcmgqcjm*

    I

    M

    MM

    M

    N

    MN;IN

    N

    N NIN IN

    NI N

    5$$

    MI

    N

    d }q{wmqw{c mjm`jm f{wpc{gc mc{kidj` g}qg bc}mcq, d `imw`gj cpc{g i f{wpc{g IN, agdwbjq nja{i~j }gbjcmgqc`jm }cwf`jmiujajm$

    Ag ikjmgj bidiucnc{jag`g dmnja wd mjm`w ajd c}g }cw mjdmjcqibj .{g}pgmqjx 7 cqibj ag mc{kid j wdw` ag i~jfgd }cw 1 ag mc{kidj wdw` ag i~jfgd*$ Mjm`w` ajd c}g cqibj g}qg agdwbjq pj{cdiujm,agdwbj{gc p{ixjdg ag `c ngqg{imjm`w` pj{cd, jc{mg` ajd mjdmj cqibjg}qg agdwbjq hw{cdiujm, ag `c ngqg{imjm`w` hw{cd5

    pj{cd

    I I

    qgq{cnja{ipj{cd

    I

    hw{cd

    I

    qgq{cnja{ihw{cdd }i`wjc wdgj ng~iug }cw pgdqiug g~j}q wd gmnj`jk{w dq{g

    hi{bc hw{cdiujm j mgc pj{cdiujm, q{gmg{gc ag `c i hi{b `c c`qc hmdaw"}g p{jd jdqg{bgajw` hi{bgj mc{kidj`jmg$ Gmnj`jk{w` g}qgagp`c}cq }p{g hi{bc pj{cdiujm, midmgdq{cjc hi{bgj mc{kidj jmghjjda hic{qg bjm$

    hw{cdiu

    .hi{bc mjm jm }gbjcmgqcjm*

    I

    M M

    MMN

    N N

    N

    IN IN

    IN

    pj{cdiu

    .hi{bc mjm jm }gbjcmgqcjm*

    I

    M M

    MM

    M

    N

    MN;IN

    N

    N N

    N

    IN IN

    INNI

    IN

    MNNI

    MN;

    caing~iu.hi{bc nja{i~jmc{kidj jm*MN;IN .MNIN*1 M

    IN

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    d }qc{g m{j}qc`jd bidiucnc{jag`g cw i }q{wmqw{ mjm`jm,hi{bc pj{cdiujm hjjda ag bw`qg i{j bcj }qckj` agmq mgchw{cdiujm$ Ag bgdjidcq m h{wmqiuc d mibpwjj }j dcqw{c`j g}qgp{gugdq d hi{bc }c hw{cdiujm$

    _gdq{w c dg`gfg xc{jgqcqgc nja{cj`i{ ag mc{kid g}qg dgmg}c{ }`wb mwdiqjd ag hgdibgdw` juibg{jg$

    3$=$ Juibg{jc mibpwj`i{ i{fcdjmj]g dwbg}m juibg{j aiw }cw bcj bw`qg }wk}qcdg c m{i{

    mibpiujjg g}qg jagdqjm .bi`gmw`g`g `i{ }dq c`mqwjqg ajd cmg`cjdwb{ j cmg`cj hg` ag cqibj*, ac{ mc{g cw p{ip{jgqj hjujmg j

    mnjbjmg agi}gkjqg, mc w{bc{g c agi}gkj{j`i{ }q{wmqw{c`g$Dw g f{gw ag xuwq m hi{bw`gj bi`gmw`c{g M;N8I j mi{g}pwda}q{wmqw{j`g c aij mibpwj ajhg{jj5

    cmii gqj jm .p$ h$ ,6>iM*

    MN= MN; INajbgqj "gqg{ .p$ h$ ";7

    iM*

    MN= I MN=

    Agic{gmg cbkjj mibpwj cw cmggcj mibpiujjg, ac{ p{gujdqp{ip{jgqj hjujmg j mnjbjmg ajhg{jqg, gj }dq juibg{j$ Mw m{gqg{gcdwb{w`wj ag cqibj ajd bi`gmw`g m{gqg j dwb{w` ag juibg{jpi}jkj`j$

    G~j}q bcj bw`qg qjpw{j ag juibg{jg$ Mc i p{jb m`c}jhjmc{g }gbgdjidgcu5 juibg{jc ag }q{wmqw{ j juibg{jc }pcjc`$

    3$=$3$ Juibg{jc ag }q{wmqw{

    @c juibg{jc ag }q{wmqw{, juibg{jj }g agi}gkg}m d mggc mgp{jxgqg }q{wmqw{c `i{, bcj g~cmq }q{wmqw{c `i{ p{jxjq d p`cd$ ]g piqagi}gkj bcj bw`qg qjpw{j ag c}gbgdgc juibg{jg5

    Juibg{jc ag mcqgd g}qg cmggc d mc{g juibg{jj ajhg{ p{jdbiaw` ag `gfc{g c` cqibj`i{ mg hi{bgcu }q{wmqw{c g}gdjc` c}wk}qcdgj$ Cmg}q qjp ag juibg{jg picqg hj j`w}q{cq p{jd g~gbp`w`5pgdqcd, juipgdqcd, dgipgdqcd, qij cxda hi{bw` k{wq M7N3; 5

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    pgdqcd

    MN= MN; MN; MN; MN=

    juipgdqcd

    MN= MN MN; MN=MN=

    dgipgdqcd

    MN= M MN=

    MN=

    MN=

    Juibg{jj ag mcqgd }g agi}gkg}m {g`cqjx pwjd dq{g gj d mggc mgp{jxgqg p{ip{jgqj`g hjujmg j mnjbjmg$

    Juibg{jc ag piujjg g}qg hi{bc ag juibg{jg ag }q{wmqw{ d mc{gjuibg{jj }g agi}gkg}m p{jd piujjc imwpcq ag `gfqw{c bw`qjp` }cwag wd }wk}qjqwgdq, i{j p{jd piujjj`g {g`cqjxg c aij }cw bcj bw`j}wk}qjqwgdj$ Mc g~gbp`w }g c{cq juibg{jc dq{g 3 kwqgd j

    ;kwqgd5

    MN; MN MN; MN=kwqgd3

    MN MN=MNMN=kwqgd;

    }cw dq{g m`i{w{j`g ag p{ipj` j juip{ipj`5

    m i{w{ ag p{ipj` m i{w{ ag juip{ipj`

    MN= M`MN; MN;

    MN=

    M`

    MN=

    MN

    }cw juibg{jc dq{g i{qi, bgqc,pc{cajbgqj`kgdugd5

    MN=

    MN=i{qi ajbgqj`kgdugd

    MN=

    MN=bgqc ajbgqj`kgdugd

    MN=N=M

    pc{c ajbgqj`kgdugd

    d mcuw` juibg{j`i{ ag piujjg, p{ip{jgqj`g `i{ mnjbjmg }gagi}gkg}m bcj bw`q agmq d mcuw` juibg{j`i{ ag mcqgd$

    Juibg{jc ag hwdmjwdg g}qg hi{bc ag juibg{jg ag }q{wmqw{d mc{g juibg{jj cw hwdmjwdj mnjbjmg ajhg{jqg$ Mc g~gbp`w }g c{cqjuibg{jc dq{g c`mii`w` c`j`jm, p{ipcdc` j cmgqid, M=N8I5

    MN; MN MN; INcmii c j jm

    MN= MN; MIN

    p{ipcdc cmgqid

    MN=MN= MI

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    3$=$; Juibg{jc }pcjc` .}qg{gijuibg{jc*

    Hi{bw`g`g m`c}jmg ag }q{wmqw{ c{cq biaw` d mc{g }dq `gfcjcqibjj dq{"i bi`gmw`, ac{ dw acw djmj i jdajmcjg c}wp{c cgu{jj

    {g`cqjxg c cqibj`i{ d }pcjw, cajm c}wp{c midhjfw{cjgj bi`gmw`g`i{$]qg{gimnjbjc mibp`gqgcu mwdiqjdg`g ag}p{g }q{wmqw{cmibkjdcjj`i{ i{fcdjmg p{jd hcpqw` m jdajm g`gbgdqg`g fgibgq{jmg{g`cqjxg `c bi`gmw`, hi{bc, }jbgq{jc j ajbgd}jwdj`g gj< gc g~p`jmg~j}qgdc juibg{jgj }pcjc`g }cw c }qg{gijuibg{jgj$

    Juibg{jc }pcjc` g}qg i hi{b ag juibg{jg `c mc{g aiw}wk}qcdg cxda cmggcj mibpiujjg j }q{wmqw{, ajhg{ p{jd piujjj`g{g`cqjxg d }pcjw c`g wdi{ cqibj mid}qjqwgdj .}cw f{wpg mid}qjqwgdqg*

    ajd bi`gmw`$ Juibg{jc }pcjc` g}qg ag aiw qjpw{j5 juibg{jcfgibgq{jm j juibg{jc ipqjm$

    3$=$;$3$ Juibg{jc fgibgq{jm .mj}"q{cd}*

    Mda d bi`gmw`c wdgj mibkjdcjj mnjbjmg aij cqibj ag mc{kid}dq wdjj p{jdq{"i `gfqw{ awk`, }j}qgbw` agxjdg pc{jc` {jfja, mggcmg c{g a{gpq w{bc{g bpjgajmc{gc {iqcjgj `jkg{g$ C}qhg`, pgdq{w aij}wk}qjqwgdj `c cqibjj ag mc{kid mw awk` `gfqw{, agxjd pi}jkj`gaiw piujjj " mda gj }g xi{ ch`c ag cmggcj pc{qg c p`cdw`wj `gfqw{jjawk`g " agmj `c aj}qcd bjdjb wdw` ag c`qw` .juibg{w` mj}"* }cwmda }g xi{ ch`c d p{j ipw}g " `c aj}qcd bc~jb .juibg{w`q{cd}"*$

    Wd g~gbp`w ag }wk}qcd mc{g c{g aij juibg{j, wdw` mj}" jc`qw` q{cd}", g}qg 3,;"ajm`i{igqj`gdc, MNM`2 MNM`5

    M

    M

    N

    N

    M`

    M`

    juibg{ mj}

    M

    M

    N

    N

    M`

    M`

    juibg{ q{cd}

    Cmg}q hg` ag }qg{gijuibg{jg g}qg agdwbjq juibg{jgfgibgq{jm }cw juibg{jg mj}"q{cd}.Kcgzg{, 3>>>*$

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    3$=$;$;$ Juibg{jc ag midhi{bcjg

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