(2013-II) 2da Practica - Cu(OH)2 (Funda II)
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Transcript of (2013-II) 2da Practica - Cu(OH)2 (Funda II)
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Cu(+2a) + 2H2O = Cu(OH)2 + 2H(+a)
T K Log(K)
C kJ J/K kJ
0 69.491 114.366 38.252 4.834E-008 -7.316
5 57.369 69.991 37.901 7.617E-008 -7.118
10 57.187 69.342 37.553 1.180E-007 -6.928
15 56.948 68.506 37.208 1.797E-007 -6.746
20 56.669 67.544 36.868 2.692E-007 -6.570
25 56.360 66.500 36.533 3.972E-007 -6.401
30 56.033 65.412 36.203 5.773E-007 -6.239
35 55.695 64.307 35.879 8.273E-007 -6.082
40 55.352 63.204 35.560 1.169E-006 -5.932
45 55.009 62.116 35.247 1.632E-006 -5.787
50 54.667 61.051 34.939 2.249E-006 -5.648
55 54.328 60.008 34.636 3.063E-006 -5.514
60 53.990 58.986 34.339 4.126E-006 -5.384
65 53.657 57.993 34.046 5.500E-006 -5.260
70 53.332 57.040 33.759 7.257E-006 -5.139
75 53.017 56.127 33.476 9.485E-006 -5.023
80 52.711 55.256 33.197 1.228E-005 -4.911
85 52.417 54.429 32.923 1.577E-005 -4.802
90 52.135 53.648 32.653 2.008E-005 -4.697
95 51.867 52.914 32.387 2.538E-005 -4.596
100 51.614 52.230 32.124 3.183E-005 -4.497
CuOH(+a) + H2O = Cu(OH)2 + H(+a)
T K Log(K)
C kJ J/K kJ
0 17.596 91.874 -7.500 2.718E+001 1.434
5 11.241 68.620 -7.846 2.975E+001 1.474
10 10.897 67.396 -8.186 3.238E+001 1.510
15 10.559 66.213 -8.520 3.504E+001 1.545
20 10.228 65.071 -8.848 3.773E+001 1.577
25 9.903 63.972 -9.171 4.044E+001 1.607
30 9.585 62.916 -9.488 4.315E+001 1.635
35 9.275 61.902 -9.800 4.585E+001 1.661
40 8.973 60.930 -10.107 4.853E+001 1.686
45 8.680 60.000 -10.409 5.119E+001 1.709
50 8.394 59.108 -10.707 5.381E+001 1.731
55 8.116 58.256 -11.000 5.639E+001 1.751
60 7.847 57.440 -11.290 5.892E+001 1.770
65 7.584 56.659 -11.575 6.139E+001 1.788
70 7.331 55.914 -11.856 6.381E+001 1.805
75 7.085 55.203 -12.134 6.617E+001 1.821
80 6.848 54.527 -12.408 6.847E+001 1.835
H S G
H
S
G
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85 6.619 53.884 -12.679 7.069E+001 1.849
90 6.399 53.274 -12.947 7.285E+001 1.862
95 6.189 52.698 -13.212 7.495E+001 1.875
100 5.987 52.155 -13.474 7.697E+001 1.886
Cu(OH)3(-a) + H(+a) = Cu(OH)2 + H2O
T K Log(K)
C kJ J/K kJ
0 -90.758 55.871 -106.020 1.888E+020 20.276
5 -83.126 83.761 -106.424 9.712E+019 19.987
10 -81.479 89.630 -106.857 5.180E+019 19.714
15 -79.811 95.469 -107.320 2.859E+019 19.456
20 -78.122 101.279 -107.812 1.629E+019 19.212
25 -76.413 107.059 -108.333 9.573E+018 18.981
30 -74.684 112.810 -108.882 5.790E+018 18.763
35 -72.935 118.531 -109.461 3.600E+018 18.556
40 -71.167 124.225 -110.068 2.298E+018 18.361
45 -69.379 129.889 -110.703 1.503E+018 18.177
50 -67.571 135.526 -111.367 1.007E+018 18.003
55 -65.745 141.135 -112.058 6.900E+017 17.839
60 -63.899 146.717 -112.778 4.830E+017 17.684
65 -62.034 152.273 -113.525 3.451E+017 17.538
70 -60.151 157.803 -114.301 2.514E+017 17.400
75 -58.248 163.307 -115.103 1.866E+017 17.271
80 -56.327 168.786 -115.934 1.410E+017 17.149
85 -54.387 174.240 -116.791 1.084E+017 17.035
90 -52.428 179.671 -117.676 8.465E+016 16.928
95 -50.451 185.079 -118.588 6.716E+016 16.827
100 -48.455 190.463 -119.527 5.409E+016 16.733
Cu(OH)4(-2a) + 2H(+a) = Cu(OH)2 + 2H2O
T K Log(K)
C kJ J/K kJ
0 -146.819 140.046 -185.072 2.480E+035 35.394
5 -132.336 192.986 -186.015 8.614E+034 34.935
10 -129.837 201.891 -187.002 3.165E+034 34.500
15 -127.307 210.745 -188.034 1.227E+034 34.089
20 -124.749 219.548 -189.109 5.001E+033 33.699
25 -122.161 228.300 -190.229 2.138E+033 33.330
30 -119.545 237.004 -191.392 9.568E+032 32.981
35 -116.899 245.658 -192.599 4.469E+032 32.650
40 -114.226 254.265 -193.849 2.175E+032 32.337
45 -111.524 262.824 -195.141 1.100E+032 32.041
H
S
G
H
S
G
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50 -108.794 271.337 -196.477 5.775E+031 31.762
55 -106.037 279.806 -197.855 3.140E+031 31.497
60 -103.251 288.230 -199.275 1.766E+031 31.247
65 -100.438 296.611 -200.737 1.025E+031 31.011
70 -97.597 304.950 -202.241 6.136E+030 30.788
75 -94.729 313.249 -203.786 3.781E+030 30.57880 -91.833 321.507 -205.373 2.396E+030 30.379
85 -88.910 329.727 -207.001 1.559E+030 30.193
90 -85.959 337.909 -208.671 1.040E+030 30.017
95 -82.980 346.054 -210.380 7.114E+029 29.852
100 -79.975 354.164 -212.131 4.980E+029 29.697
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[H(+a)] pH [Cu(+2a)] [CuOH(+a)] [Cu(OH)3(-a)]
1.00E+00 0.0 2.517E+006 2.473E-002 1.045E-019
3.16E-01 0.5 2.517E+005 7.820E-003 3.303E-019
1.00E-01 1.0 2.517E+004 2.473E-003 1.045E-018
3.16E-02 1.5 2.517E+003 7.820E-004 3.303E-018
1.00E-02 2.0 2.517E+002 2.473E-004 1.045E-017
3.16E-03 2.5 2.517E+001 7.820E-005 3.303E-017
1.00E-03 3.0 2.517E+000 2.473E-005 1.045E-016
3.16E-04 3.5 2.517E-001 7.820E-006 3.303E-016
1.00E-04 4.0 2.517E-002 2.473E-006 1.045E-015
3.16E-05 4.5 2.517E-003 7.820E-007 3.303E-015
1.00E-05 5.0 2.517E-004 2.473E-007 1.045E-014
3.16E-06 5.5 2.517E-005 7.820E-008 3.303E-014
1.00E-06 6.0 2.517E-006 2.473E-008 1.045E-013
3.16E-07 6.5 2.517E-007 7.820E-009 3.303E-013
1.00E-07 7.0 2.517E-008 2.473E-009 1.045E-012
3.16E-08 7.5 2.517E-009 7.820E-010 3.303E-012
1.00E-08 8.0 2.517E-010 2.473E-010 1.045E-011
3.16E-09 8.5 2.517E-011 7.820E-011 3.303E-011
1.00E-09 9.0 2.517E-012 2.473E-011 1.045E-010
3.16E-10 9.5 2.517E-013 7.820E-012 3.303E-010
1.00E-10 10.0 2.517E-014 2.473E-012 1.045E-009
3.16E-11 10.5 2.517E-015 7.820E-013 3.303E-009
1.00E-11 11.0 2.517E-016 2.473E-013 1.045E-008
3.16E-12 11.5 2.517E-017 7.820E-014 3.303E-008
1.00E-12 12.0 2.517E-018 2.473E-014 1.045E-007
3.16E-13 12.5 2.517E-019 7.820E-015 3.303E-007
1.00E-13 13.0 2.517E-020 2.473E-015 1.045E-006
3.16E-14 13.5 2.517E-021 7.820E-016 3.303E-006
1.00E-14 14.0 2.517E-022 2.473E-016 1.045E-005
3.16E-15 14.5 2.517E-023 7.820E-017 3.303E-005
1.00E-15 15.0 2.517E-024 2.473E-017 1.045E-004
3.16E-16 15.5 2.517E-025 7.820E-018 3.303E-004
1.00E-16 16.0 2.517E-026 2.473E-018 1.045E-003
3.16E-17 16.5 2.517E-027 7.820E-019 3.303E-003
1.00E-17 17.0 2.517E-028 2.473E-019 1.045E-002
3.16E-18 17.5 2.517E-029 7.820E-020 3.303E-002
1.00E-18 18.0 2.517E-030 2.473E-020 1.045E-001
3.16E-19 18.5 2.517E-031 7.820E-021 3.303E-001
1.00E-19 19.0 2.517E-032 2.473E-021 1.045E+000
3.16E-20 19.5 2.517E-033 7.820E-022 3.303E+000
1.00E-20 20.0 2.517E-034 2.473E-022 1.045E+001
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0 1 2 3 4 5 6 7 8 9
0%
5%
10%
15%
20%
25%
30%
35%
40%45%
50%
55%
60%
65%
70%
75%
80%
85%
90%
95%
100%
Diagrama de P
"
# Co!e$ra!i%
0 1 2 3 4 5 6 7 8 9 10
-15
-10
-5
0
5
Diagrama
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-45
-40
-35
-30
-25
-20
"H
ogCuT*
0 1 2 3 4 5 6 7 8 9
1.000E-043
1.000E-039
1.000E-035
1.000E-031
1.000E-027
1.000E-023
1.000E-019
1.000E-015
1.000E-011
1.000E-007
1.000E-003
1.000E+001
Diagrama
ogCuT*
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[Cu(OH)4(-2a)] [CuT] [Cu(+2a)]/[CuT] [CuOH(+a)]/[CuT]
4.67636871E-034 2.517E+006 1.000E+000 9.823E-009
4.67636871E-033 2.517E+005 1.000E+000 3.106E-008
4.67636871E-032 2.517E+004 1.000E+000 9.823E-008
4.67636871E-031 2.517E+003 1.000E+000 3.106E-007
4.67636871E-030 2.517E+002 1.000E+000 9.823E-007
4.67636871E-029 2.517E+001 1.000E+000 3.106E-006
4.67636871E-028 2.518E+000 1.000E+000 9.823E-006
4.67636871E-027 2.518E-001 1.000E+000 3.106E-005
4.67636871E-026 2.518E-002 9.999E-001 9.822E-005
4.67636871E-025 2.518E-003 9.997E-001 3.105E-004
4.67636871E-024 2.520E-004 9.990E-001 9.814E-004
4.67636871E-023 2.525E-005 9.969E-001 3.097E-003
4.67636871E-022 2.542E-006 9.903E-001 9.728E-003
4.67636871E-021 2.596E-007 9.699E-001 3.013E-002
4.67636871E-020 2.765E-008 9.105E-001 8.944E-002
4.67636871E-019 3.303E-009 7.622E-001 2.368E-001
4.67636871E-018 5.095E-010 4.941E-001 4.854E-001
4.67636871E-017 1.364E-010 1.846E-001 5.733E-001
4.67636871E-016 1.317E-010 1.911E-002 1.878E-001
4.67636871E-015 3.384E-010 7.439E-004 2.311E-002
4.67636871E-014 1.047E-009 2.404E-005 2.362E-003
4.67636871E-013 3.305E-009 7.618E-007 2.366E-004
4.67636871E-012 1.045E-008 2.409E-008 2.366E-005
4.67636871E-011 3.308E-008 7.610E-010 2.364E-006
4.67636871E-010 1.049E-007 2.399E-011 2.357E-007
4.67636871E-009 3.350E-007 7.514E-013 2.334E-008
4.67636871E-008 1.091E-006 2.307E-014 2.266E-009
4.67636871E-007 3.771E-006 6.676E-016 2.074E-010
4.67636871E-006 1.512E-005 1.665E-017 1.635E-011
4.67636871E-005 7.980E-005 3.155E-019 9.800E-013
0.0004676369 5.721E-004 4.400E-021 4.323E-014
0.0046763687 5.007E-003 5.028E-023 1.562E-015
0.0467636871 4.781E-002 5.266E-025 5.173E-017
0.4676368714 4.709E-001 5.346E-027 1.661E-018
4.6763687136 4.687E+000 5.371E-029 5.276E-020
46.7636871361 4.680E+001 5.380E-031 1.671E-021
467.6368713609 4.677E+002 5.382E-033 5.287E-023
4676.368713609 4.677E+003 5.383E-035 1.672E-024
46763.68713609 4.676E+004 5.383E-037 5.288E-026
467636.8713609 4.676E+005 5.383E-039 1.672E-027
4676368.713609 4.676E+006 5.383E-041 5.288E-029
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10 11 12 13 14 15 16 17 18 19 20
edomia!ia
[Cu(+2a)]/[CuT]
[CuOH(+a)]/[CuT]
[Cu(OH)3(-a)]/[CuT]
[Cu(OH)4(-2a)]/[CuT]
11 12 13 14 15 16 17 18 19 20
e &'errum
log[Cu(+2a)]
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log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
10 11 12 13 14 15 16 17 18 19 20
e &'errum
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
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[Cu(OH)3(-a)]/[CuT] [Cu(OH)4(-2a)]/[CuT] log[CuT] log[Cu(+2a)]
4.150E-026 1.858E-040 6.4009655703 6.400965566
1.312E-024 1.858E-038 5.4009655795 5.400965566
4.149E-023 1.858E-036 4.4009656087 4.400965566
1.312E-021 1.858E-034 3.4009657009 3.400965566
4.149E-020 1.858E-032 2.4009659926 2.400965566
1.312E-018 1.858E-030 1.4009669151 1.400965566
4.149E-017 1.858E-028 0.4009698322 0.400965566
1.312E-015 1.858E-026 -0.5990209434 -0.599034434
4.149E-014 1.857E-024 -1.5989917744 -1.599034434
1.312E-012 1.857E-022 -2.5988995468 -2.599034434
4.145E-011 1.856E-020 -3.5986080263 -3.599034434
1.308E-009 1.852E-018 -4.597687443 -4.599034434
4.109E-008 1.839E-016 -5.5947890635 -5.599034434
1.273E-006 1.802E-014 -6.5857483637 -6.599034434
3.778E-005 1.691E-012 -7.5583238531 -7.599034434
1.000E-003 1.416E-010 -8.481117259 -8.599034434
2.050E-002 9.179E-009 -9.2928631952 -9.599034434
2.422E-001 3.428E-007 -9.865150235 -10.599034434
7.931E-001 3.550E-006 -9.8803799111 -11.599034434
9.761E-001 1.382E-005 -9.47054808 -12.599034434
9.976E-001 4.466E-005 -8.9799818981 -13.599034434
9.996E-001 1.415E-004 -8.4808740446 -14.599034434
9.995E-001 4.474E-004 -7.9808339765 -15.599034434
9.986E-001 1.414E-003 -7.4804232466 -16.599034434
9.955E-001 4.457E-003 -6.9790987134 -17.599034434
9.860E-001 1.396E-002 -6.4749337659 -18.599034434
9.572E-001 4.285E-002 -5.9620196429 -19.599034434
8.760E-001 1.240E-001 -5.4235390461 -20.599034434
6.908E-001 3.092E-001 -4.820372342 -21.599034434
4.140E-001 5.860E-001 -4.0980096134 -22.599034434
1.826E-001 8.174E-001 -3.2425283562 -23.599034434
6.598E-002 9.340E-001 -2.3004476616 -24.599034434
2.185E-002 9.781E-001 -1.320496568 -25.599034434
7.014E-003 9.930E-001 -0.3270341689 -26.599034434
2.229E-003 9.978E-001 0.6708778099 -27.599034434
7.059E-004 9.993E-001 1.670215425 -28.599034434
2.233E-004 9.998E-001 2.67000575 -29.599034434
7.064E-005 9.999E-001 3.6699394239 -30.599034434
2.234E-005 1.000E+000 4.6699184476 -31.599034434
7.064E-006 1.000E+000 5.6699118141 -32.599034434
2.234E-006 1.000E+000 6.6699097164 -33.599034434
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-40
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-5
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5
10
Diagrama de
"H
ogCuT*
0 1 2 3 4 5 6 7 8 9 10 1
0
5
10
Diagrama de
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-15
-10
-5
"H
ogCuT*
5 6 7 8 9 10
-10
-9
-8
-7
-6
-5
-4
Diagrama de
ogCuT*
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solu!l!"a"
log[CuOH(+a)] log[Cu(OH)3(-a)] log[Cu(OH)4(-2a)] log([Cu(+2a)]/[CuT])
-1.6067805747 -18.9810386358 -33.3300912537 -4.266170123424E-009
-2.1067805747 -18.4810386358 -32.3300912537 -1.349081427183E-008
-2.6067805747 -17.9810386358 -31.3300912537 -4.266169916634E-008
-3.1067805747 -17.4810386358 -30.3300912537 -1.349081240161E-007
-3.6067805747 -16.9810386358 -29.3300912537 -4.266168034843E-007
-4.1067805747 -16.4810386358 -28.3300912537 -1.349079354265E-006
-4.6067805747 -15.9810386358 -27.3300912537 -4.266149176278E-006
-5.1067805747 -15.4810386358 -26.3300912537 -1.349060496353E-005
-5.6067805747 -14.9810386358 -25.3300912537 -4.265960607798E-005
-6.1067805747 -14.4810386358 -24.3300912537 -0.0001348872
-6.6067805747 -13.9810386358 -23.3300912537 -0.0004264076
-7.1067805747 -13.4810386358 -22.3300912537 -0.001346991
-7.6067805747 -12.9810386358 -21.3300912537 -0.0042453704
-8.1067805747 -12.4810386358 -20.3300912537 -0.0132860703
-8.6067805747 -11.9810386358 -19.3300912537 -0.0407105808
-9.1067805747 -11.4810386358 -18.3300912537 -0.1179171749
-9.6067805747 -10.9810386358 -17.3300912537 -0.3061712388
-10.1067805747 -10.4810386358 -16.3300912537 -0.733884199
-10.6067805747 -9.9810386358 -15.3300912537 -1.7186545228
-11.1067805747 -9.4810386358 -14.3300912537 -3.128486354
-11.6067805747 -8.9810386358 -13.3300912537 -4.6190525359
-12.1067805747 -8.4810386358 -12.3300912537 -6.1181603893
-12.6067805747 -7.9810386358 -11.3300912537 -7.6182004575
-13.1067805747 -7.4810386358 -10.3300912537 -9.1186111874
-13.6067805747 -6.9810386358 -9.3300912537 -10.6199357205
-14.1067805747 -6.4810386358 -8.3300912537 -12.1241006681
-14.6067805747 -5.9810386358 -7.3300912537 -13.6370147911
-15.1067805747 -5.4810386358 -6.3300912537 -15.1754953878
-15.6067805747 -4.9810386358 -5.3300912537 -16.778662092
-16.1067805747 -4.4810386358 -4.3300912537 -18.5010248206
-16.6067805747 -3.9810386358 -3.3300912537 -20.3565060778
-17.1067805747 -3.4810386358 -2.3300912537 -22.2985867724
-17.6067805747 -2.9810386358 -1.3300912537 -24.278537866
-18.1067805747 -2.4810386358 -0.3300912537 -26.2720002651
-18.6067805747 -1.9810386358 0.6699087463 -28.2699122439
-19.1067805747 -1.4810386358 1.6699087463 -30.2692498589
-19.6067805747 -0.9810386358 2.6699087463 -32.269040184
-20.1067805747 -0.4810386358 3.6699087463 -34.2689738579
-20.6067805747 0.0189613642 4.6699087463 -36.2689528816
-21.1067805747 0.5189613642 5.6699087463 -38.2689462481
-21.6067805747 1.0189613642 6.6699087463 -40.2689441504
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12 13 14 15 16 17 18 19 20
Souiidad
log[CuT]
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
EC# #1 #2 & #3
12 13 14 15 16 17 18 19 20
Souiidad
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log[CuT]
EC# #1 #2 & #3
11 12 13 14 15
Souiidad
log[CuT]
EC# #1 #2 & #3
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log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT]) log([Cu(OH)4(-2a)]/[CuT])
-8.0077461449 -25.3820042061 -39.731056824
-7.5077461542 -23.8820042153 -37.7310568332
-7.0077461833 -22.3820042444 -35.7310568624
-6.5077462756 -20.8820043367 -33.7310569547
-6.0077465673 -19.3820046284 -31.7310572464-5.5077474898 -17.8820055509 -29.7310581688
-5.0077504068 -16.3820084679 -27.7310610859
-4.5077596313 -14.8820176924 -25.7310703104
-4.0077888003 -13.3820468614 -23.7310994794
-3.5078810279 -11.882139089 -21.7311917069
-3.0081725483 -10.3824306094 -19.7314832274
-2.5090931317 -8.8833511928 -17.7324038107
-2.0119915111 -7.3862495722 -15.7353021902
-1.521032211 -5.8952902721 -13.74434289
-1.0484567215 -4.4227147826 -11.7717674006-0.6256633156 -2.9999213767 -9.8489739947
-0.3139173795 -1.6881754406 -8.0372280585
-0.2416303397 -0.6158884008 -6.4649410187
-0.7264006635 -0.1006587246 -5.4497113426
-1.6362324947 -0.0104905558 -4.8595431737
-2.6267986766 -0.0010567377 -4.3501093557
-3.62590653 -0.0001645911 -3.8492172091
-4.6259465982 -0.0002046593 -3.3492572772
-5.6263573281 -0.0006153892 -2.8496680071
-6.6276818612 -0.0019399223 -2.3509925403
-7.6318468087 -0.0061048698 -1.8551574878
-8.6447609318 -0.0190189929 -1.3680716109
-9.6832415285 -0.0574995896 -0.9065522076
-10.7864082327 -0.1606662938 -0.5097189117
-12.0087709613 -0.3830290224 -0.2320816403
-13.3642522185 -0.7385102796 -0.0875628976
-14.8063329131 -1.1805909742 -0.0296435921
-16.2862840067 -1.6605420678 -0.0095946857
-17.7797464058 -2.1540044669 -0.0030570848
-19.2776583846 -2.6519164457 -0.0009690637
-20.7769959996 -3.1512540607 -0.0003066787
-22.2767863247 -3.6510443858 -9.700372829371E-005
-23.7767199985 -4.1509780597 -3.06776148275104E-005
-25.2766990223 -4.6509570834 -9.70134788841223E-006
-26.7766923888 -5.1509504499 -3.06785899957048E-006
-28.2766902911 -5.6509483522 -9.70144540900842E-007
EC# Cu #1 2
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'g/ #2 2
'g/ #3 2
EC# * #1 3.15E-05
'ol/ #2 3.15E-05
'ol/ #3 3.15E-05
EC# * #1 -4,.2.
log['ol/] #2 -4,.2.
log['ol/] #3 -4,.2.
E* g*,al las '!*as sul* ,aaa, o* ",*as " ,s!"
E* l ,a*go " 55 a 142 u'pl o* los l'!s p,'!s!l*o "'os ",*os " 10.5 u 11 po, p,au!* pa,a
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! l pH pa,a s aso ua " 60 a 80 po"'os "!,
l'!s p,'!s!ls.
Os,a'os * la g,:a a"u*a u !s u* '*!'o logl pH;88.
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3.15E-05
os *o 'u& !"os.
p,o sa'os uo "aa, las u,as.
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u u'pl o* los
[CuT];-990 ua*"o"!, u s
a"as).
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Cu(+2a) + 2H2O = Cu(OH)2 + 2H(+a)
T K
C kJ J/K kJ
0 69.491 114.366 38.252 4.834E-008
5 57.369 69.991 37.901 7.617E-00810 57.187 69.342 37.553 1.180E-007
15 56.948 68.506 37.208 1.797E-007
20 56.669 67.544 36.868 2.692E-007
25 56.360 66.500 36.533 3.972E-007
30 56.033 65.412 36.203 5.773E-007
35 55.695 64.307 35.879 8.273E-007
40 55.352 63.204 35.560 1.169E-006
45 55.009 62.116 35.247 1.632E-006
50 54.667 61.051 34.939 2.249E-006
55 54.328 60.008 34.636 3.063E-00660 53.990 58.986 34.339 4.126E-006
65 53.657 57.993 34.046 5.500E-006
70 53.332 57.040 33.759 7.257E-006
75 53.017 56.127 33.476 9.485E-006
80 52.711 55.256 33.197 1.228E-005
85 52.417 54.429 32.923 1.577E-005
90 52.135 53.648 32.653 2.008E-005
95 51.867 52.914 32.387 2.538E-005
100 51.614 52.230 32.124 3.183E-005
CuOH(+a) + H2O = Cu(OH)2 + H(+a)
T K
C kJ J/K kJ
0 17.596 91.874 -7.500 2.718E+001
5 11.241 68.620 -7.846 2.975E+001
10 10.897 67.396 -8.186 3.238E+001
15 10.559 66.213 -8.520 3.504E+001
20 10.228 65.071 -8.848 3.773E+001
25 9.903 63.972 -9.171 4.044E+001
30 9.585 62.916 -9.488 4.315E+001
35 9.275 61.902 -9.800 4.585E+001
40 8.973 60.930 -10.107 4.853E+001
45 8.680 60.000 -10.409 5.119E+001
50 8.394 59.108 -10.707 5.381E+001
55 8.116 58.256 -11.000 5.639E+001
60 7.847 57.440 -11.290 5.892E+001
H S G
H S G
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65 7.584 56.659 -11.575 6.139E+001
70 7.331 55.914 -11.856 6.381E+001
75 7.085 55.203 -12.134 6.617E+001
80 6.848 54.527 -12.408 6.847E+001
85 6.619 53.884 -12.679 7.069E+001
90 6.399 53.274 -12.947 7.285E+001
95 6.189 52.698 -13.212 7.495E+001100 5.987 52.155 -13.474 7.697E+001
Cu(OH)3(-a) + H(+a) = Cu(OH)2 + H2O
T K
C kJ J/K kJ
0 -90.758 55.871 -106.020 1.888E+020
5 -83.126 83.761 -106.424 9.712E+019
10 -81.479 89.630 -106.857 5.180E+01915 -79.811 95.469 -107.320 2.859E+019
20 -78.122 101.279 -107.812 1.629E+019
25 -76.413 107.059 -108.333 9.573E+018
30 -74.684 112.810 -108.882 5.790E+018
35 -72.935 118.531 -109.461 3.600E+018
40 -71.167 124.225 -110.068 2.298E+018
45 -69.379 129.889 -110.703 1.503E+018
50 -67.571 135.526 -111.367 1.007E+018
55 -65.745 141.135 -112.058 6.900E+017
60 -63.899 146.717 -112.778 4.830E+017
65 -62.034 152.273 -113.525 3.451E+017
70 -60.151 157.803 -114.301 2.514E+017
75 -58.248 163.307 -115.103 1.866E+017
80 -56.327 168.786 -115.934 1.410E+017
85 -54.387 174.240 -116.791 1.084E+017
90 -52.428 179.671 -117.676 8.465E+016
95 -50.451 185.079 -118.588 6.716E+016
100 -48.455 190.463 -119.527 5.409E+016
Cu(OH)4(-2a) + 2H(+a) = Cu(OH)2 + 2H2O
T K
C kJ J/K kJ
0 -146.819 140.046 -185.072 2.480E+035
5 -132.336 192.986 -186.015 8.614E+034
10 -129.837 201.891 -187.002 3.165E+034
15 -127.307 210.745 -188.034 1.227E+034
H S G
H S G
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20 -124.749 219.548 -189.109 5.001E+033
25 -122.161 228.300 -190.229 2.138E+033
30 -119.545 237.004 -191.392 9.568E+032
35 -116.899 245.658 -192.599 4.469E+032
40 -114.226 254.265 -193.849 2.175E+032
45 -111.524 262.824 -195.141 1.100E+032
50 -108.794 271.337 -196.477 5.775E+031
55 -106.037 279.806 -197.855 3.140E+031
60 -103.251 288.230 -199.275 1.766E+031
65 -100.438 296.611 -200.737 1.025E+031
70 -97.597 304.950 -202.241 6.136E+030
75 -94.729 313.249 -203.786 3.781E+030
80 -91.833 321.507 -205.373 2.396E+030
85 -88.910 329.727 -207.001 1.559E+030
90 -85.959 337.909 -208.671 1.040E+030
95 -82.980 346.054 -210.380 7.114E+029100 -79.975 354.164 -212.131 4.980E+029
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[H(+a)] pH [Cu(+2a)]
Log(K) 1.00E+00 0.0 1.313E+007
3.16E-01 0.5 1.313E+006
-7.316 1.00E-01 1.0 1.313E+005
-7.118 3.16E-02 1.5 1.313E+004-6.928 1.00E-02 2.0 1.313E+003
-6.746 3.16E-03 2.5 1.313E+002
-6.570 1.00E-03 3.0 1.313E+001
-6.401 3.16E-04 3.5 1.313E+000
-6.239 1.00E-04 4.0 1.313E-001
-6.082 3.16E-05 4.5 1.313E-002
-5.932 1.00E-05 5.0 1.313E-003
-5.787 3.16E-06 5.5 1.313E-004
-5.648 1.00E-06 6.0 1.313E-005
-5.514 3.16E-07 6.5 1.313E-006-5.384 1.00E-07 7.0 1.313E-007
-5.260 3.16E-08 7.5 1.313E-008
-5.139 1.00E-08 8.0 1.313E-009
-5.023 3.16E-09 8.5 1.313E-010
-4.911 1.00E-09 9.0 1.313E-011
-4.802 3.16E-10 9.5 1.313E-012
-4.697 1.00E-10 10.0 1.313E-013
-4.596 3.16E-11 10.5 1.313E-014
-4.497 1.00E-11 11.0 1.313E-015
3.16E-12 11.5 1.313E-016
1.00E-12 12.0 1.313E-017
3.16E-13 12.5 1.313E-018
1.00E-13 13.0 1.313E-019
Log(K) 3.16E-14 13.5 1.313E-020
1.00E-14 14.0 1.313E-021
1.434 3.16E-15 14.5 1.313E-022
1.474 1.00E-15 15.0 1.313E-023
1.510 3.16E-16 15.5 1.313E-024
1.545 1.00E-16 16.0 1.313E-025
1.577 3.16E-17 16.5 1.313E-026
1.607 1.00E-17 17.0 1.313E-027
1.635 3.16E-18 17.5 1.313E-028
1.661 1.00E-18 18.0 1.313E-029
1.686 3.16E-19 18.5 1.313E-030
1.709 1.00E-19 19.0 1.313E-031
1.731 3.16E-20 19.5 1.313E-032
1.751 1.00E-20 20.0 1.313E-033
1.770
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1.788
1.805
1.821
1.835
1.849
1.862
1.8751.886
Log(K)
20.276
19.987
19.71419.456
19.212
18.981
18.763
18.556
18.361
18.177
18.003
17.839
17.684
17.538
17.400
17.271
17.149
17.035
16.928
16.827
16.733
Log(K)
35.394
34.935
34.500
34.089
0
0%
5%
10%15%
20%
25%
30%
35%
40%
45%
50%
55%60%
65%
70%
75%
80%
85%
90%
95%
100%
D
# Co!e$ra!i%
0 1 2 3
0
5
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33.699
33.330
32.981
32.650
32.337
32.041
31.762
31.497
31.247
31.011
30.788
30.578
30.379
30.193
30.017
29.85229.697
-45
-40
-35
-30
-25
-20
-15
-10
-5
ogCuT*
0 1 2
1.000E-023
1.000E-019
1.000E-015
1.000E-011
1.000E-007
1.000E-003
1.000E+001
ogCuT*
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1.000E-043
1.000E-039
1.000E-035
1.000E-031
1.000E-027
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[CuOH(+a)] [Cu(OH)3(-a)] [Cu(OH)4(-2a)] [CuT] [Cu(+2a)]/[CuT]
3.361E-002 1.030E-020 1.16096670E-035 1.313E+007 1.000E+000
1.063E-002 3.256E-020 1.16096670E-034 1.313E+006 1.000E+000
3.361E-003 1.030E-019 1.16096670E-033 1.313E+005 1.000E+000
1.063E-003 3.256E-019 1.16096670E-032 1.313E+004 1.000E+0003.361E-004 1.030E-018 1.16096670E-031 1.313E+003 1.000E+000
1.063E-004 3.256E-018 1.16096670E-030 1.313E+002 1.000E+000
3.361E-005 1.030E-017 1.16096670E-029 1.313E+001 1.000E+000
1.063E-005 3.256E-017 1.16096670E-028 1.313E+000 1.000E+000
3.361E-006 1.030E-016 1.16096670E-027 1.313E-001 1.000E+000
1.063E-006 3.256E-016 1.16096670E-026 1.313E-002 9.999E-001
3.361E-007 1.030E-015 1.16096670E-025 1.313E-003 9.997E-001
1.063E-007 3.256E-015 1.16096670E-024 1.314E-004 9.992E-001
3.361E-008 1.030E-014 1.16096670E-023 1.316E-005 9.974E-001
1.063E-008 3.256E-014 1.16096670E-022 1.323E-006 9.920E-0013.361E-009 1.030E-013 1.16096670E-021 1.346E-007 9.750E-001
1.063E-009 3.256E-013 1.16096670E-020 1.419E-008 9.251E-001
3.361E-010 1.030E-012 1.16096670E-019 1.650E-009 7.957E-001
1.063E-010 3.256E-012 1.16096670E-018 2.408E-010 5.451E-001
3.361E-011 1.030E-011 1.16096670E-017 5.704E-011 2.302E-001
1.063E-011 3.256E-011 1.16096670E-016 4.450E-011 2.950E-002
3.361E-012 1.030E-010 1.16096670E-015 1.065E-010 1.233E-003
1.063E-012 3.256E-010 1.16096670E-014 3.267E-010 4.019E-005
3.361E-013 1.030E-009 1.16096670E-013 1.030E-009 1.275E-006
1.063E-013 3.256E-009 1.16096670E-012 3.257E-009 4.031E-008
3.361E-014 1.030E-008 1.16096670E-011 1.031E-008 1.274E-009
1.063E-014 3.256E-008 1.16096670E-010 3.268E-008 4.018E-011
3.361E-015 1.030E-007 1.16096670E-009 1.041E-007 1.261E-012
1.063E-015 3.256E-007 1.16096670E-008 3.372E-007 3.893E-014
3.361E-016 1.030E-006 1.16096670E-007 1.146E-006 1.146E-015
1.063E-016 3.256E-006 0.000001161 4.417E-006 2.972E-017
3.361E-017 1.030E-005 1.16096670E-005 2.191E-005 5.993E-019
1.063E-017 3.256E-005 0.0001160967 1.487E-004 8.831E-021
3.361E-018 1.030E-004 0.0011609667 1.264E-003 1.039E-022
1.063E-018 3.256E-004 0.011609667 1.194E-002 1.100E-024
3.361E-019 1.030E-003 0.1160966696 1.171E-001 1.121E-026
1.063E-019 3.256E-003 1.1609666956 1.164E+000 1.128E-028
3.361E-020 1.030E-002 11.6096669557 1.162E+001 1.130E-030
1.063E-020 3.256E-002 116.0966695573 1.161E+002 1.131E-032
3.361E-021 1.030E-001 1160.966695573 1.161E+003 1.131E-034
1.063E-021 3.256E-001 11609.66695573 1.161E+004 1.131E-036
3.361E-022 1.030E+000 116096.6695573 1.161E+005 1.131E-038
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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
iagrama de Predomia!ia
[Cu(
[CuO
[Cu(
[Cu(
"H
4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Diagrama de &'errum
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"H
3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Diagrama de &'errum
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"H
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[CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT] [Cu(OH)4(-2a)]/[CuT] log[CuT]
2.560E-009 7.843E-028 8.843E-043 7.1182174532
8.096E-009 2.480E-026 8.843E-041 6.1182174556
2.560E-008 7.843E-025 8.843E-039 5.1182174632
8.096E-008 2.480E-023 8.843E-037 4.11821748732.560E-007 7.843E-022 8.843E-035 3.1182175633
8.096E-007 2.480E-020 8.843E-033 2.1182178037
2.560E-006 7.843E-019 8.843E-031 1.118218564
8.096E-006 2.480E-017 8.843E-029 0.1182209682
2.560E-005 7.842E-016 8.843E-027 -0.8817714291
8.096E-005 2.480E-014 8.842E-025 -1.881747388
2.560E-004 7.841E-013 8.841E-023 -2.8816713724
8.090E-004 2.478E-011 8.836E-021 -3.8814310773
2.554E-003 7.823E-010 8.820E-019 -4.880672071
8.031E-003 2.460E-008 8.772E-017 -5.87828056582.496E-002 7.647E-007 8.622E-015 -6.8708031929
7.490E-002 2.294E-005 8.181E-013 -7.8479622148
2.037E-001 6.240E-004 7.036E-011 -8.782513566
4.413E-001 1.352E-002 4.821E-009 -9.6182839684
5.893E-001 1.805E-001 2.035E-007 -10.2438424037
2.388E-001 7.316E-001 2.609E-006 -10.3516228852
3.157E-002 9.672E-001 1.091E-005 -9.972828585
3.254E-003 9.967E-001 3.554E-005 -9.4858720027
3.263E-004 9.996E-001 1.127E-004 -8.9871290844
3.263E-005 9.996E-001 3.564E-004 -8.4871513244
3.261E-006 9.989E-001 1.126E-003 -7.9868295069
3.253E-007 9.964E-001 3.553E-003 -7.4857744072
3.228E-008 9.889E-001 1.115E-002 -6.9824507937
3.152E-009 9.656E-001 3.443E-002 -6.4721045568
2.934E-010 8.987E-001 1.013E-001 -5.9409203518
2.406E-011 7.372E-001 2.628E-001 -5.3548793677
1.534E-012 4.700E-001 5.300E-001 -4.6594382906
7.150E-014 2.190E-001 7.810E-001 -3.8278166388
2.659E-015 8.146E-002 9.185E-001 -2.898277207
8.906E-017 2.728E-002 9.727E-001 -1.9231679919
2.870E-018 8.791E-003 9.912E-001 -0.9313455909
9.130E-020 2.797E-003 9.972E-001 0.066036048
2.893E-021 8.861E-004 9.991E-001 1.0652047534
9.153E-023 2.804E-004 9.997E-001 2.0649415435
2.895E-024 8.868E-005 9.999E-001 3.064858276
9.155E-026 2.804E-005 1.000E+000 4.0648319411
2.895E-027 8.869E-006 1.000E+000 5.064823613
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2a)]/[CuT]
(+a)]/[CuT]
H)3(-a)]/[CuT]
H)4(-2a)]/[CuT]
0 1 2 3 4 5 6 7
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
Diagr
ogCuT*
0 1 2 3 4 5 6 7
10
Diagr
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-15
-10
-5
0
5
ogCuT*
5 6 7 8
-8
-7
-6
-5
-4
Diagr
ogCuT*
log[Cu(+2a)]
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[Cu(OH)4(-2a)]
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[Cu(OH)4(-2a)]
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-11
-10
-9
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log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)] log[Cu(OH)4(-2a)]
7.1182174521 -1.473502094 -19.9873203414 -34.9351802386
6.1182174521 -1.973502094 -19.4873203414 -33.9351802386
5.1182174521 -2.473502094 -18.9873203414 -32.9351802386
4.1182174521 -2.973502094 -18.4873203414 -31.93518023863.1182174521 -3.473502094 -17.9873203414 -30.9351802386
2.1182174521 -3.973502094 -17.4873203414 -29.9351802386
1.1182174521 -4.473502094 -16.9873203414 -28.9351802386
0.1182174521 -4.973502094 -16.4873203414 -27.9351802386
-0.8817825479 -5.473502094 -15.9873203414 -26.9351802386
-1.8817825479 -5.973502094 -15.4873203414 -25.9351802386
-2.8817825479 -6.473502094 -14.9873203414 -24.9351802386
-3.8817825479 -6.973502094 -14.4873203414 -23.9351802386
-4.8817825479 -7.473502094 -13.9873203414 -22.9351802386
-5.8817825479 -7.973502094 -13.4873203414 -21.9351802386-6.8817825479 -8.473502094 -12.9873203414 -20.9351802386
-7.8817825479 -8.973502094 -12.4873203414 -19.9351802386
-8.8817825479 -9.473502094 -11.9873203414 -18.9351802386
-9.8817825479 -9.973502094 -11.4873203414 -17.9351802386
-10.8817825479 -10.473502094 -10.9873203414 -16.9351802386
-11.8817825479 -10.973502094 -10.4873203414 -15.9351802386
-12.8817825479 -11.473502094 -9.9873203414 -14.9351802386
-13.8817825479 -11.973502094 -9.4873203414 -13.9351802386
-14.8817825479 -12.473502094 -8.9873203414 -12.9351802386
-15.8817825479 -12.973502094 -8.4873203414 -11.9351802386
-16.8817825479 -13.473502094 -7.9873203414 -10.9351802386
-17.8817825479 -13.973502094 -7.4873203414 -9.9351802386
-18.8817825479 -14.473502094 -6.9873203414 -8.9351802386
-19.8817825479 -14.973502094 -6.4873203414 -7.9351802386
-20.8817825479 -15.473502094 -5.9873203414 -6.9351802386
-21.8817825479 -15.973502094 -5.4873203414 -5.9351802386
-22.8817825479 -16.473502094 -4.9873203414 -4.9351802386
-23.8817825479 -16.973502094 -4.4873203414 -3.9351802386
-24.8817825479 -17.473502094 -3.9873203414 -2.9351802386
-25.8817825479 -17.973502094 -3.4873203414 -1.9351802386
-26.8817825479 -18.473502094 -2.9873203414 -0.9351802386
-27.8817825479 -18.973502094 -2.4873203414 0.0648197614
-28.8817825479 -19.473502094 -1.9873203414 1.0648197614
-29.8817825479 -19.973502094 -1.4873203414 2.0648197614
-30.8817825479 -20.473502094 -0.9873203414 3.0648197614
-31.8817825479 -20.973502094 -0.4873203414 4.0648197614
-32.8817825479 -21.473502094 0.0126796586 5.0648197614
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8 9 10 11 12 13 14 15 16 17 18 19 20
ma de Souiidad
log[Cu
log[Cu(
log[Cu
log[Cu(
log[Cu(
EC# #1
"H
8 9 10 11 12 13 14 15 16 17 18 19 20
ma de Souiidad
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log[C
EC#
"H
10 11 12 13 14 15 16
ama de Souiidad
log[C
EC#
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"H
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log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT])
-1.111897535856E-009 -8.5917195472 -27.1055377946
-3.516128653043E-009 -8.0917195496 -25.605537797
-1.111897514915E-008 -7.5917195572 -24.1055378046
-3.516128573816E-008 -7.0917195812 -22.6055378286-1.111897386988E-007 -6.5917196572 -21.1055379046
-3.516127294550E-007 -6.0917198977 -19.6055381451
-1.111896106032E-006 -5.5917206579 -18.1055389054
-3.516114484158E-006 -5.0917230622 -16.6055413096
-1.111883296078E-005 -4.5917306649 -15.1055489123
-3.515986390286E-005 -4.0917547059 -13.6055729533
-0.0001111755 -3.5918307216 -12.105648969
-0.0003514706 -3.0920710167 -10.6058892641
-0.0011104769 -2.592830023 -9.1066482704
-0.0035019821 -2.0952215282 -7.6090397756-0.010979355 -1.602698901 -6.1165171484
-0.0338203331 -1.1255398791 -4.6393581265
-0.0992689819 -0.690988528 -3.2048067754
-0.2634985795 -0.3552181255 -1.8690363729
-0.6379401442 -0.2296596903 -0.7434779377
-1.5301596627 -0.6218792088 -0.1356974562
-2.9089539629 -1.5006735089 -0.0144917564
-4.3959105452 -2.4876300913 -0.0014483387
-5.8946534635 -3.4863730095 -0.0001912569
-7.3946312235 -4.4863507695 -0.0001690169
-8.894953041 -5.486672587 -0.0004908344
-10.3960081407 -6.4877276867 -0.0015459341
-11.8993317542 -7.4910513003 -0.0048695477
-13.4096779911 -8.5013975371 -0.0152157845
-14.9408621961 -9.5325817422 -0.0463999896
-16.5269031802 -10.6186227263 -0.1324409737
-18.2223442573 -11.8140638033 -0.3278820508
-20.0539659091 -13.1456854551 -0.6595037025
-21.9835053409 -14.5752248869 -1.0890431343
-23.958614556 -16.050334102 -1.5641523494
-25.950436957 -17.5421565031 -2.0559747505
-27.9478185959 -19.039538142 -2.5533563894
-29.9469873013 -20.5387068473 -3.0525250947
-31.9467240914 -22.0384436374 -3.5522618848
-33.9466408239 -23.5383603699 -4.0521786173
-35.946614489 -25.0383340351 -4.5521522825
-37.9466061609 -26.538325707 -5.0521439544
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EC# Cu #1
'g/ #2
'g/ #3
EC# * #1
'ol/ #2
'ol/ #3
EC# * #1
log['ol/] #2
log['ol/] #3
]
+2a)]
H(+a)]
OH)3(-a)]
OH)4(-2a)]
#2 & #3
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E* g*,al las '!*as sul* ,aaa,E* l ,a*go " 59 a 151 u'pl o* l
*o "'os ",*os " 10.5 u 11! l pH pa,a s aso ua " 60
l'!s p,'!s!ls.
Os,a'os * la g,:a a"u*a u
l pH;93.
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log([Cu(OH)4(-2a)]/[CuT])
-42.0533976918
-40.0533976942
-38.0533977018
-36.0533977259-34.0533978019
-32.0533980423
-30.0533988026
-28.0534012068
-26.0534088095
-24.0534328506
-22.0535088662
-20.0537491613
-18.0545081676
-16.0568996729-14.0643770457
-12.0872180238
-10.1526666726
-8.3168962702
-6.6913378349
-5.5835573534
-4.9623516536
-4.4493082359
-3.9480511542
-3.4480289142
-2.9483507317
-2.4494058314
-1.9527294449
-1.4630756818
-0.9942598868
-0.5803008709
-0.275741948
-0.1073635998
-0.0369030316
-0.0120122467
-0.0038346477
-0.0012162866
-0.000384992
-0.0001217821
-3.85145609211515E-005
-1.21797428358182E-005
-3.85160979724862E-006
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2
2
2
3.15E-05
3.15E-05
3.15E-05
-4,.2.2
-4,.2.2
-4,.2.2
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o* ",*as " ,s!"uos *o 'u& !"os.os l'!s p,'!s!ls p,o sa'os u
o, p,au!* pa,a *o "aa, las u,as.80 po"'os "!, u u'pl o* los
!s u* '*!'o log[CuT];-104 ua*"o
o*lus!* po"'os "!, u s!=a*"o ,oas a,o*aa"as).
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Cu(+2a) + 2H2O = Cu(OH)2 + 2H(+a)
T K
C kJ J/K kJ
0 69.491 114.366 38.252 4.834E-008
5 57.369 69.991 37.901 7.617E-008
10 57.187 69.342 37.553 1.180E-007
15 56.948 68.506 37.208 1.797E-007
20 56.669 67.544 36.868 2.692E-007
25 56.360 66.500 36.533 3.972E-007
30 56.033 65.412 36.203 5.773E-007
35 55.695 64.307 35.879 8.273E-007
40 55.352 63.204 35.560 1.169E-006
45 55.009 62.116 35.247 1.632E-006
50 54.667 61.051 34.939 2.249E-006
55 54.328 60.008 34.636 3.063E-006
60 53.990 58.986 34.339 4.126E-006
65 53.657 57.993 34.046 5.500E-006
70 53.332 57.040 33.759 7.257E-006
75 53.017 56.127 33.476 9.485E-006
80 52.711 55.256 33.197 1.228E-005
85 52.417 54.429 32.923 1.577E-005
90 52.135 53.648 32.653 2.008E-005
95 51.867 52.914 32.387 2.538E-005
100 51.614 52.230 32.124 3.183E-005
CuOH(+a) + H2O = Cu(OH)2 + H(+a)
T K
C kJ J/K kJ
0 17.596 91.874 -7.500 2.718E+001
5 11.241 68.620 -7.846 2.975E+001
10 10.897 67.396 -8.186 3.238E+001
15 10.559 66.213 -8.520 3.504E+001
20 10.228 65.071 -8.848 3.773E+001
25 9.903 63.972 -9.171 4.044E+001
30 9.585 62.916 -9.488 4.315E+001
35 9.275 61.902 -9.800 4.585E+001
40 8.973 60.930 -10.107 4.853E+001
45 8.680 60.000 -10.409 5.119E+001
50 8.394 59.108 -10.707 5.381E+001
55 8.116 58.256 -11.000 5.639E+001
60 7.847 57.440 -11.290 5.892E+001
65 7.584 56.659 -11.575 6.139E+001
70 7.331 55.914 -11.856 6.381E+001
75 7.085 55.203 -12.134 6.617E+001
H S G
H S G
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80 6.848 54.527 -12.408 6.847E+001
85 6.619 53.884 -12.679 7.069E+001
90 6.399 53.274 -12.947 7.285E+001
95 6.189 52.698 -13.212 7.495E+001
100 5.987 52.155 -13.474 7.697E+001
Cu(OH)3(-a) + H(+a) = Cu(OH)2 + H2O
T K
C kJ J/K kJ
0 -90.758 55.871 -106.020 1.888E+020
5 -83.126 83.761 -106.424 9.712E+019
10 -81.479 89.630 -106.857 5.180E+019
15 -79.811 95.469 -107.320 2.859E+019
20 -78.122 101.279 -107.812 1.629E+019
25 -76.413 107.059 -108.333 9.573E+018
30 -74.684 112.810 -108.882 5.790E+018
35 -72.935 118.531 -109.461 3.600E+018
40 -71.167 124.225 -110.068 2.298E+018
45 -69.379 129.889 -110.703 1.503E+018
50 -67.571 135.526 -111.367 1.007E+018
55 -65.745 141.135 -112.058 6.900E+017
60 -63.899 146.717 -112.778 4.830E+017
65 -62.034 152.273 -113.525 3.451E+017
70 -60.151 157.803 -114.301 2.514E+017
75 -58.248 163.307 -115.103 1.866E+017
80 -56.327 168.786 -115.934 1.410E+017
85 -54.387 174.240 -116.791 1.084E+017
90 -52.428 179.671 -117.676 8.465E+016
95 -50.451 185.079 -118.588 6.716E+016
100 -48.455 190.463 -119.527 5.409E+016
CuO2(-2a) + 2H(+a) = Cu(OH)2
T K
C kJ J/K kJ
0 -148.217 173.046 -195.484 2.430E+037
5 -146.021 181.013 -196.370 7.585E+036
10 -144.062 187.994 -197.293 2.506E+036
15 -142.286 194.211 -198.248 8.723E+035
20 -140.648 199.848 -199.234 3.186E+035
25 -139.110 205.050 -200.246 1.217E+035
30 -137.642 209.934 -201.284 4.845E+034
35 -136.220 214.588 -202.345 2.007E+03440 -134.826 219.076 -203.429 8.623E+033
45 -133.447 223.443 -204.536 3.837E+033
H S G
H S G
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50 -132.078 227.714 -205.664 1.765E+033
55 -130.715 231.900 -206.813 8.376E+032
60 -129.360 235.997 -207.982 4.096E+032
65 -128.003 240.040 -209.173 2.060E+032
70 -126.633 244.061 -210.383 1.065E+032
75 -125.248 248.068 -211.613 5.649E+03180 -123.845 252.070 -212.864 3.072E+031
85 -122.420 256.076 -214.134 1.710E+031
90 -120.971 260.096 -215.424 9.743E+030
95 -119.492 264.138 -216.735 5.673E+030
100 -117.982 268.213 -218.066 3.373E+030
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[H(+a)] pH [Cu(+2a)]
Log(K) 1.00E+00 0.0 3.940E+004
3.16E-01 0.5 3.940E+003
-7.316 1.00E-01 1.0 3.940E+002
-7.118 3.16E-02 1.5 3.940E+001
-6.928 1.00E-02 2.0 3.940E+000
-6.746 3.16E-03 2.5 3.940E-001
-6.570 1.00E-03 3.0 3.940E-002
-6.401 3.16E-04 3.5 3.940E-003
-6.239 1.00E-04 4.0 3.940E-004
-6.082 3.16E-05 4.5 3.940E-005
-5.932 1.00E-05 5.0 3.940E-006
-5.787 3.16E-06 5.5 3.940E-007
-5.648 1.00E-06 6.0 3.940E-008
-5.514 3.16E-07 6.5 3.940E-009
-5.384 1.00E-07 7.0 3.940E-010
-5.260 3.16E-08 7.5 3.940E-011
-5.139 1.00E-08 8.0 3.940E-012
-5.023 3.16E-09 8.5 3.940E-013
-4.911 1.00E-09 9.0 3.940E-014
-4.802 3.16E-10 9.5 3.940E-015
-4.697 1.00E-10 10.0 3.940E-016
-4.596 3.16E-11 10.5 3.940E-017
-4.497 1.00E-11 11.0 3.940E-018
3.16E-12 11.5 3.940E-019
1.00E-12 12.0 3.940E-020
3.16E-13 12.5 3.940E-021
1.00E-13 13.0 3.940E-022
Log(K) 3.16E-14 13.5 3.940E-023
1.00E-14 14.0 3.940E-024
1.434 3.16E-15 14.5 3.940E-025
1.474 1.00E-15 15.0 3.940E-026
1.510 3.16E-16 15.5 3.940E-027
1.545 1.00E-16 16.0 3.940E-028
1.577 3.16E-17 16.5 3.940E-029
1.607 1.00E-17 17.0 3.940E-030
1.635 3.16E-18 17.5 3.940E-031
1.661 1.00E-18 18.0 3.940E-032
1.686 3.16E-19 18.5 3.940E-033
1.709 1.00E-19 19.0 3.940E-034
1.731 3.16E-20 19.5 3.940E-035
1.751 1.00E-20 20.0 3.940E-036
1.770
1.788
1.805
1.821
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1.835
1.849
1.862
1.875
1.886
Log(K)
20.276
19.987
19.714
19.456
19.212
18.981
18.763
18.556
18.361
18.177
18.003
17.839
17.684
17.538
17.400
17.271
17.149
17.035
16.928
16.827
16.733
Log(K)
37.386
36.880
36.399
35.941
35.503
35.085
34.685
34.30233.936
33.584
0
0%
5%
10%
15%
20%
25%
30%
35%
40%
45%
50%
55%
60%
65%
70%
75%
80%
85%
90%
95%
100%
D
# Co!e$ra!i%
0 1 2 3
-15
-10
-5
0
5
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33.247
32.923
32.612
32.314
32.027
31.75231.487
31.233
30.989
30.754
30.528
-50
-45
-40
-35
-30
-25
-20ogCuT*
0 1 2
1.000E-047
1.000E-043
1.000E-039
1.000E-035
1.000E-031
1.000E-027
1.000E-023
1.000E-019
1.000E-015
1.000E-011
1.000E-007
1.000E-003
1.000E+001
ogCuT*
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[CuOH(+a)] [Cu(OH)3(-a)] [CuO2(-2a)] [CuT] [Cu(+2a)]/[CuT]
1.334E-002 1.489E-017 1.762801E-031 3.940E+004 1.000E+000
4.219E-003 4.708E-017 1.762801E-030 3.940E+003 1.000E+000
1.334E-003 1.489E-016 1.762801E-029 3.940E+002 1.000E+000
4.219E-004 4.708E-016 1.762801E-028 3.941E+001 1.000E+000
1.334E-004 1.489E-015 1.762801E-027 3.941E+000 1.000E+000
4.219E-005 4.708E-015 1.762801E-026 3.941E-001 9.999E-001
1.334E-005 1.489E-014 1.762801E-025 3.942E-002 9.997E-001
4.219E-006 4.708E-014 1.762801E-024 3.945E-003 9.989E-001
1.334E-006 1.489E-013 1.762801E-023 3.954E-004 9.966E-001
4.219E-007 4.708E-013 1.762801E-022 3.983E-005 9.894E-001
1.334E-007 1.489E-012 1.762801E-021 4.074E-006 9.672E-001
4.219E-008 4.708E-012 1.762801E-020 4.362E-007 9.033E-001
1.334E-008 1.489E-011 1.762801E-019 5.276E-008 7.468E-001
4.219E-009 4.708E-011 1.762801E-018 8.207E-009 4.801E-001
1.334E-009 1.489E-010 1.762801E-017 1.877E-009 2.099E-001
4.219E-010 4.708E-010 1.762801E-016 9.322E-010 4.227E-002
1.334E-010 1.489E-009 1.762801E-015 1.626E-009 2.423E-003
4.219E-011 4.708E-009 1.762801E-014 4.751E-009 8.294E-005
1.334E-011 1.489E-008 1.762801E-013 1.490E-008 2.644E-006
4.219E-012 4.708E-008 1.762801E-012 4.709E-008 8.368E-008
1.334E-012 1.489E-007 1.762801E-011 1.489E-007 2.646E-009
4.219E-013 4.708E-007 1.762801E-010 4.710E-007 8.366E-011
1.334E-013 1.489E-006 1.762801E-009 1.491E-006 2.643E-012
4.219E-014 4.708E-006 1.762801E-008 4.726E-006 8.338E-014
1.334E-014 1.489E-005 1.762801E-007 1.507E-005 2.616E-015
4.219E-015 4.708E-005 1.762801E-006 4.885E-005 8.067E-017
1.334E-015 1.489E-004 0.000017628 1.665E-004 2.366E-018
4.219E-016 4.708E-004 0.0001762801 6.471E-004 6.089E-020
1.334E-016 1.489E-003 0.0017628005 3.252E-003 1.212E-021
4.219E-017 4.708E-003 0.0176280053 2.234E-002 1.764E-023
1.334E-017 1.489E-002 0.1762800526 1.912E-001 2.061E-025
4.219E-018 4.708E-002 1.7628005258 1.810E+000 2.177E-027
1.334E-018 1.489E-001 17.6280052582 1.778E+001 2.217E-029
4.219E-019 4.708E-001 176.280052582 1.768E+002 2.229E-031
1.334E-019 1.489E+000 1762.80052582 1.764E+003 2.233E-033
4.219E-020 4.708E+000 17628.0052582 1.763E+004 2.235E-035
1.334E-020 1.489E+001 176280.052582 1.763E+005 2.235E-037
4.219E-021 4.708E+001 1762800.52582 1.763E+006 2.235E-039
1.334E-021 1.489E+002 17628005.2582 1.763E+007 2.235E-041
4.219E-022 4.708E+002 176280052.582 1.763E+008 2.235E-043
1.334E-022 1.489E+003 1762800525.82 1.763E+009 2.235E-045
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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
iagrama de Predomia!ia
[Cu(
[Cu
[Cu(
[Cu
"H
4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Diagrama de &'errum
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"H
3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Diagrama de &'errum
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"H
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[CuOH(+a)]/[CuT] [Cu(OH)3(-a)]/[CuT] [CuO2(-2a)]/[CuT] log[CuT]
3.386E-007 3.778E-022 4.474E-036 4.5955478202
1.071E-006 1.195E-020 4.474E-034 3.5955481382
3.386E-006 3.778E-019 4.474E-032 2.5955491437
1.071E-005 1.195E-017 4.474E-030 1.5955523235
3.386E-005 3.778E-016 4.473E-028 0.5955623788
1.071E-004 1.195E-014 4.473E-026 -0.4044058251
3.385E-004 3.777E-013 4.472E-024 -1.4043052923
1.070E-003 1.194E-011 4.469E-022 -2.4039875328
3.375E-003 3.766E-010 4.458E-020 -3.4029842161
1.059E-002 1.182E-008 4.426E-018 -4.3998266148
3.275E-002 3.655E-007 4.327E-016 -5.3899897227
9.672E-002 1.079E-005 4.041E-014 -6.3602686007
2.529E-001 2.822E-004 3.341E-012 -7.2776734329
5.141E-001 5.737E-003 2.148E-010 -8.0858153093
7.108E-001 7.931E-002 9.390E-009 -8.7264791611
4.526E-001 5.051E-001 1.891E-007 -9.0305009811
8.205E-002 9.155E-001 1.084E-006 -8.7888094941
8.881E-003 9.910E-001 3.710E-006 -8.3232253749
8.954E-004 9.991E-001 1.183E-005 -7.8267424065
8.961E-005 9.999E-001 3.744E-005 -7.3270825094
8.961E-006 9.999E-001 1.184E-004 -6.827082414
8.958E-007 9.996E-001 3.743E-004 -6.3269747625
8.951E-008 9.988E-001 1.183E-003 -5.8266237963
8.928E-009 9.963E-001 3.730E-003 -5.3255147379
8.857E-010 9.883E-001 1.170E-002 -4.822026005
8.638E-011 9.639E-001 3.609E-002 -4.3111745516
8.013E-012 8.941E-001 1.059E-001 -3.7785417087
6.520E-013 7.276E-001 2.724E-001 -3.1890231996
4.103E-014 4.579E-001 5.421E-001 -2.4878909482
1.889E-015 2.108E-001 7.892E-001 -1.6509890537
6.980E-017 7.788E-002 9.221E-001 -0.7185826655
2.331E-018 2.601E-002 9.740E-001 0.2576505788
7.506E-020 8.375E-003 9.916E-001 1.2498558863
2.387E-021 2.664E-003 9.973E-001 2.2473615861
7.563E-023 8.439E-004 9.992E-001 3.2465698285
2.393E-024 2.670E-004 9.997E-001 4.246319152
7.569E-026 8.445E-005 9.999E-001 5.246239851
2.394E-027 2.671E-005 1.000E+000 6.2462147708
7.569E-029 8.446E-006 1.000E+000 7.2462068395
2.394E-030 2.671E-006 1.000E+000 8.2462043313
7.569E-032 8.446E-007 1.000E+000 9.2462035382
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+2a)]/[CuT]
H(+a)]/[CuT]
OH)3(-a)]/[CuT]
2(-2a)]/[CuT]
0 1 2 3 4 5 6 7
-40
-35
-30
-25
-20
-15
-10
-5
0
5
10
15
Diagr
ogCuT*
0 1 2 3 4 5 6 7
5
10
15
Diagr
log[Cu(+2a)]
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-10
-5
0
ogCuT*
4 5 6 7
-10
-9
-8
-7
-6
-5
-4
Diagr
ogCuT*
log[CuOH(+a)]
log[Cu(OH)3(-a)]
log[CuO2(-2a)]
[Cu(+2a)]
[CuOH(+a)]
[Cu(OH)3(-a)]
[CuO2(-2a)]
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log[Cu(+2a)] log[CuOH(+a)] log[Cu(OH)3(-a)] log[CuO2(-2a)]
4.5955476731 -1.874743614 -16.8271377229 -30.7537968286
3.5955476731 -2.374743614 -16.3271377229 -29.7537968286
2.5955476731 -2.874743614 -15.8271377229 -28.7537968286
1.5955476731 -3.374743614 -15.3271377229 -27.7537968286
0.5955476731 -3.874743614 -14.8271377229 -26.7537968286
-0.4044523269 -4.374743614 -14.3271377229 -25.7537968286
-1.4044523269 -4.874743614 -13.8271377229 -24.7537968286
-2.4044523269 -5.374743614 -13.3271377229 -23.7537968286
-3.4044523269 -5.874743614 -12.8271377229 -22.7537968286
-4.4044523269 -6.374743614 -12.3271377229 -21.7537968286
-5.4044523269 -6.874743614 -11.8271377229 -20.7537968286
-6.4044523269 -7.374743614 -11.3271377229 -19.7537968286
-7.4044523269 -7.874743614 -10.8271377229 -18.7537968286
-8.4044523269 -8.374743614 -10.3271377229 -17.7537968286
-9.4044523269 -8.874743614 -9.8271377229 -16.7537968286
-10.4044523269 -9.374743614 -9.3271377229 -15.7537968286
-11.4044523269 -9.874743614 -8.8271377229 -14.7537968286
-12.4044523269 -10.374743614 -8.3271377229 -13.7537968286
-13.4044523269 -10.874743614 -7.8271377229 -12.7537968286
-14.4044523269 -11.374743614 -7.3271377229 -11.7537968286
-15.4044523269 -11.874743614 -6.8271377229 -10.7537968286
-16.4044523269 -12.374743614 -6.3271377229 -9.7537968286
-17.4044523269 -12.874743614 -5.8271377229 -8.7537968286
-18.4044523269 -13.374743614 -5.3271377229 -7.7537968286
-19.4044523269 -13.874743614 -4.8271377229 -6.7537968286
-20.4044523269 -14.374743614 -4.3271377229 -5.7537968286
-21.4044523269 -14.874743614 -3.8271377229 -4.7537968286
-22.4044523269 -15.374743614 -3.3271377229 -3.7537968286
-23.4044523269 -15.874743614 -2.8271377229 -2.7537968286
-24.4044523269 -16.374743614 -2.3271377229 -1.7537968286
-25.4044523269 -16.874743614 -1.8271377229 -0.7537968286
-26.4044523269 -17.374743614 -1.3271377229 0.2462031714
-27.4044523269 -17.874743614 -0.8271377229 1.2462031714
-28.4044523269 -18.374743614 -0.3271377229 2.2462031714
-29.4044523269 -18.874743614 0.1728622771 3.2462031714
-30.4044523269 -19.374743614 0.6728622771 4.2462031714
-31.4044523269 -19.874743614 1.1728622771 5.2462031714
-32.4044523269 -20.374743614 1.6728622771 6.2462031714
-33.4044523269 -20.874743614 2.1728622771 7.2462031714
-34.4044523269 -21.374743614 2.6728622771 8.2462031714
-35.4044523269 -21.874743614 3.1728622771 9.2462031714
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8 9 10 11 12 13 14 15 16 17 18 19 20
ama de Souiidad
log[C
log[C
log[C
log[C
log[C
EC#
"H
8 9 10 11 12 13 14 15 16 17 18 19 20
ama de Souiidad
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log[C
EC#
"H
8 9 10 11 12 13
ama de Souiidad
log[C
EC#
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"H
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log([Cu(+2a)]/[CuT]) log([CuOH(+a)]/[CuT]) log([Cu(OH)3(-a)]/[CuT])
-1.470594545275E-007 -6.4702914342 -21.4226855431
-0.000000465 -5.9702917522 -19.922685861
-1.470592303976E-006 -5.4702927577 -18.4226868666
-4.650404165441E-006 -4.9702959376 -16.9226900464-1.470569895973E-005 -4.4703059928 -15.4227001017
-4.650180097750E-005 -3.9703377889 -13.9227318978
-0.0001470346 -3.4704383217 -12.4228324306
-0.0004647941 -2.9707560813 -10.9231501901
-0.0014681107 -2.4717593979 -9.4241535067
-0.0046257121 -1.9749169993 -7.9273111081
-0.0144626042 -1.4847538913 -6.4371480002
-0.0441837262 -1.0144750134 -4.9668691222
-0.1267788939 -0.5970701811 -3.5494642899
-0.3186370176 -0.2889283047 -2.2413224136-0.6779731657 -0.1482644529 -1.1006585617
-1.3739513457 -0.3442426329 -0.2966367417
-2.6156428328 -1.0859341199 -0.0383282288
-4.0812269519 -2.0515182391 -0.0039123479
-5.5777099203 -3.0480012075 -0.0003953164
-7.0773698175 -4.0476611047 -5.52135126577917E-005
-8.5773699129 -5.0476612 -5.53088644354248E-005
-10.0774775644 -6.0477688516 -0.0001629604
-11.5778285306 -7.0481198177 -0.0005139266
-13.078937589 -8.0492288761 -0.001622985
-14.5824263218 -9.052717609 -0.0051117178
-16.0932777753 -10.0635690624 -0.0159631713
-17.6259106182 -11.0962019054 -0.0485960142
-19.2154291273 -12.1857204144 -0.1381145233
-20.9165613787 -13.3868526659 -0.3392467747
-22.7534632732 -14.7237545603 -0.6761486692
-24.6858696614 -16.1561609485 -1.1085550574
-26.6621029057 -17.6323941928 -1.5847883017
-28.6543082132 -19.1245995003 -2.0769936092
-30.651813913 -20.6221052002 -2.574499309
-32.6510221553 -22.1213134425 -3.0737075513
-34.6507714789 -23.621062766 -3.5734568749
-36.6506921779 -25.120983465 -4.0733775739
-38.6506670977 -26.6209583849 -4.5733524937
-40.6506591664 -28.1209504535 -5.0733445624
-42.6506566582 -29.6209479454 -5.5733420542
-44.6506558651 -31.1209471522 -6.0733412611
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EC# Cu #1
'g/ #2
'g/ #3
EC# * #1
'ol/ #2
'ol/ #3
EC# * #1
log['ol/] #2
log['ol/] #3
E* g*,al las '!*as sul* ,aaa,E* l ,a*go " 46 a 123 u'pl o* l*o "'os ",*os " 10.5 u 11
T]
(+2a)]
OH(+a)]
(OH)3(-a)]
O2(-2a)]
1 #2 & #3
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! l pH pa,a s aso ua " 60
l'!s p,'!s!ls.
Os,a'os * la g,:a a"u*a ul pH;75.
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log([CuO2(-2a)]/[CuT])
-35.3493446488
-33.3493449668
-31.3493459723
-29.3493491522-27.3493592074
-25.3493910035
-23.3494915363
-21.3498092959
-19.3508126125
-17.3539702139
-15.3638071059
-13.393528228
-11.4761233957
-9.6679815193
-8.0273176675
-6.7232958475
-5.9649873345
-5.4305714537
-4.9270544221
-4.4267143193
-3.9267144146
-3.4268220662
-2.9271730323
-2.4282820907
-1.9317708236
-1.442622277
-0.97525512
-0.564773629
-0.2659058805
-0.1028077749
-0.0352141631
-0.0114474074
-0.0036527149
-0.0011584148
-0.0003666571
-0.0001159806
-3.6679641059815E-005
-1.1599455878888E-005
-3.6681035141089E-006
-0.00000116
-3.6681174560845E-007
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2
2
2
3.15E-05
3.15E-05
3.15E-05
-4,.2.2
-4,.2.2
-4,.2.2
o* ",*as " ,s!"uos *o 'u& !"os.os l'!s p,'!s!ls p,o sa'os uo, p,au!* pa,a *o "aa, las u,as.
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80 po"'os "!, u u'pl o* los
!s u* '*!'o log[CuT];-903 ua*"oo*lus!* po"'os "!, u s!=a*"o ,oas a,o*aa"as).
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